‑ Place the contaminated material in a sealable plastic bag and remove the excess air.
Seal the bag.
‑ Place a cup of vermiculite in a second bag, place the first bag in the second and seal it.
‑ Clean the area with plenty of water and keep cleaning with water and soap.
‑ Dispose of the hazardous material in accordance with the local legislation in force.
• First aid in the event of contact with the electrolyte
EYES
Immediately wash the eyes in abundant running water for at least 15 minutes, keeping
the eyelids open and flushing the eye and back of the eyelid. Immediately seek medical
help.
SKIN
Wash in cold water under a shower, remove contaminated garments. Continue washing
for at least 15 minutes. Seek medical help where necessary.
RESPIRATORY TRACT
Move the casualty outdoors into the open air. If the casualty has difficulty breathing,
have oxygen administered by trained personnel. If breathing stops, apply mouth‑to‑
mouth resuscitation and immediately seek emergency medical help.
7.22.3.4 Lithium battery fire
All metals may burn in certain conditions, which depend on certain factors such as: physical
state, presence of oxidising atmospheres and severity of the source of ignition. Alkali metals
such as lithium may burn in normal atmospheres. In addition, lithium reacts explosively
with water to form hydrogen and the presence of small quantities of water may set fire to the
material and the hydrogen gas that is released. Once metal fires start they are very hard to
extinguish with ordinary equipment. This is partly due to the strong heat produced by the
burning metal, whose temperature may reach 1000°C. In addition, lithium may react with
certain materials commonly used in fire extinguishers, like water and CO2.
Special extinguishers are required, designed for controlling and extinguishing lithium fires.
In particular, graphite‑based extinguishers (Lith‑x) are used. Usually these extinguishers
work by forming a crust or a layer of material on the surface of the burning metal. Lith‑x,
which is a common graphite‑based agent, may be used with an extinguisher or spread over
the fire. In the event of lithium fire, the room may fill with a dense white smoke, mostly for‑
med by lithium oxide and other metal oxides. This condition may cause serious damage to
the respiratory tract, skin and eyes. All precautions needed to limit exposure to these fumes
must be adopted. It should be noted that this procedure is applicable only to fires on indivi‑
dual cells. Larger fires have to be managed only by professionally trained personnel. Finally,
it should be noted that in the presence of combustible materials other than lithium it is advi‑
sable to use different types of extinguishers in conjunction to better ensure the extinguishing
action of each on the appropriate material, however do not use water or CO2 extinguishers
directly on lithium fires.
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